Extraction of Sodium and Uses of Its Important Compounds

Sodium compounds had been known for some timecombined in a molten mixture in which the presence of
prior to 1807, when English chemist Sir Humphrey Davycalcium chloride lowers the melting point of the sodium
(1778-1829) succeeded in isolating sodium itself. Thechloride by more than 30%. When an electric current is
element is represented by a chemical symbol (Na),passed through the mixture, sodium ions move to the
reflecting its Latin name ‘natrium’. In its purecathode, where they pick up electrons to become
form, sodium has a bright, shiny surface, but in order tosodium atoms. At the same time, ions of chlorine
preserve this appearance, it must be stored in oil:migrate to the anode, losing electrons to become
sodium reacts quickly with oxygen, forming a whitechlorine atoms. Sodium is a low-density material that
crust of sodium oxide. Pure sodium never occurs infloats on water, and in the Downs cell, the molten
nature; instead, it combines readily with othersodium rises to the top, where it is drawn off. The
substances to form compounds, many of which arechlorine gas is allowed to escape through a vent at the
among the most widely used chemicals in industry. It istop of the anode end of the cell, and the resulting
also highly soluble: thus whereas sodium and potassiumsodium metal, that is, the elemental form of sodium, is
occur in crystal rocks at about the same ratio, sodiumabout 99.8% pure.
is about 30 times more abundant in sea-water than itsSodium chloride is by far the most widely known and
sister element.commonly used sodium compound and this in itself is a
 Though the extraction of sodium involves the use ofdistinction, given the fact that so many sodium
a special process, the metal is plentiful in the form ofcompounds are a part of our daily life. Today people
sodium chloride, better known as table salt. In fact, thethink of salt primarily as a seasoning to enhance the
term salt in chemistry refers generally to anytaste of food, but prior to the development of
combination of a metal with a nonmetal. Morerefrigeration, it was vital as a preservative because it
specifically, salts are (along with water) the product ofkept microbes away from otherwise perishable food
reactions between acids and bases. Sodium chloride isitems. Salt does not merely improve the taste of food;
so easy to obtain, and therefore so cheap, that mostit is an essential nutrient. Sodium compounds regulate
industries making other sodium compounds use it,transmission of signals through the nervous system,
simply separating out the chloride before adding otheralter the permeability of membranes, and perform a
elements. The United States is the world's largestnumber of other life-preserving functions. On the other
producer of sodium chloride, obtained primarily fromhand, too much salt can aggravate high blood
brine, a term used to describe any solution of sodiumpressure. Thus, since the 1970s and 1980s, food
chloride in water. Brine comes from seawater,manufacturers have increasingly offered products low
subterranean wells, and desert lakes, such as thein sodium, a major selling point for health-conscious
Great Salt Lake in Utah. Another source of sodiumconsumers.
chloride is rock salt, created underground by theIn addition to its widespread use in consumer goods,
evaporation of long-buried saltwater seas. Other topsodium chloride is the principal source of sodium used
sodium-chloride-producing nations include China,in making other sodium compounds. These include
Germany, Great Britain, France, India, and varioussodium hydroxide, for manufacturing cellulose products
countries in the former Soviet Union. Salt may besuch as film, rayon, soaps, and paper, and for refining
cheap and plentiful for the world in general, but therepetroleum. In its application as a cleaning solution,
are places where it is a precious commodity. Onesodium hydroxide is known as caustic soda or lye.
such place is the Sahara Desert, where salt caravansAnother widely used sodium compound is sodium
ply a brisk trade today, much as they have sincecarbonate or, soda ash, applied in glass-making, paper
ancient times.production, textile manufacturing, and other areas, such
Modern methods for the production of sodiumas the production of soaps and detergents. Sodium
represent an improvement in the technique Davy usedalso can be combined with carbon to produce sodium
in 1807, although the basic principle is the same. Thoughbicarbonate, or baking soda. Sodium sulfate,
several decades passed before electricity came intosometimes known as salt cake, is used for making
widespread public use, scientists had been studying itscardboard and Kraft paper. Yet another widely used
properties for years, and Davy applied it in a processsodium compound is sodium silicate, or "water glass,"
called electrolysis. Electrolysis is the use of an electricused in the production of soaps, detergents, and
current to produce a chemical reaction, in this case, toadhesives; in water treatment; and in bleaching and
separate sodium from the other element or elementssizing of textiles. Still other sodium compounds used by
with which it is combined. Davy first fused or melted aindustry and/or consumers include sodium borate, or
sample of sodium chloride, then electrolyzed it. Using anborax; sodium tartrate, or sal tartar; the explosive
electrode, a device that conducts electricity and issodium nitrate, or Chilean salt-peter; and the food
used to emit or collect electric charge, he separatedadditive monosodium glutamate (MSG). Perhaps
the sodium chloride in such a way that liquid sodiumironically, there are few uses for pure metallic sodium.
metal collected on the cathode, or negatively chargedOnce applied as an "anti-knock" additive in leaded
end. Meanwhile, the gaseous chlorine was releasedgasoline, before those products were phased out for
through the anode, or the positively charged end. Theenvironmental reasons, metallic sodium is now used as
apparatus used for sodium separation today is knowna heat-exchange medium in nuclear reactors. But its
as the Downs cell, after its inventor, J. C. Downs. In awidest application is in the production of the many
Downs cell, sodium chloride and calcium chloride areother sodium compounds used around the world.